Wednesday 17 April 2013

Depletion of Ozone

The Script

Tian Tian: Good morning everyone. We are officers from the National Environment Agency Singapore. Today we will bring you through various aspects of the ozone.
They are mainly the importance of the ozone layer, the depletion of ozone from the reaction with CFCs, the sources, effects and solutions of unburnt hydrocarbons and photochemical smog.
Firstly, we would like to talk about importance of the ozone layer. As we know, the ozone layer is able to absorb ultraviolet radiation, commonly known as UV, at high altitudes. This prevents the harmful UV radiation from reaching the surface of the earth. UV radiation is very destructive to organic matter and humans are largely affected by UV radiation as exposure could lead to an increase in the risk of cancer, cataracts and an impaired immune system. Plants cannot live and grow in heavy ultraviolet radiation, nor can the plankton that serve as food for most of the ocean life. Thus the ozone layer is very important to life on Earth.

Seraphina: Secondly, we will be talking about the depletion of ozone from the reaction with CFCs. Chlorofluorocarbons (CFCs), commonly known as CFCs, are a family of chemical compounds developed back in the 1930s as safe, non-toxic, non-flammable alternatives to dangerous substances like ammonia for purposes of refrigeration and spray can propellants. Their usage grew enormously over the years. One of the elements that make up CFCs is chlorine. Very little chlorine exists naturally in the atmosphere. But it turns out that CFCs are an excellent way of introducing chlorine into the ozone layer. The ultraviolet radiation at this altitude breaks down CFCs, freeing the chlorine. Some problems involved with the depletion of the ozone layer are that under the proper conditions, chlorine gas has the potential to destroy large amounts of ozone. This has indeed been observed, especially over Antarctica. As a consequence, levels of genetically harmful ultraviolet radiation have increased. It also damages and mutates the DNA of marine bacteria and the larvae of starfish and urchins. Some research also shows that a decreased ozone layer will increase rates of malaria and other infectious diseases.  According to the EPA, 17 million more cases of cataracts can also be expected. It also results in certain cases of skin cancer.

Michelle: Thirdly, we will go in depth towards the sources, effects and solutions of unburnt hydrocarbons. Hydrocarbons come from the combustion of engine exhausts, oil refineries, oil-fuelled power plants, evaporation from petroleum fuels, solvents, dry cleaning solutions and paints. Unburnt hydrocarbon may form ozone with oxides of nitrogen which is a central nervous system depressant. Since hydrocarbons come from engine exhausts, there are solutions to reduce engine emissions. Modern car engines now carefully control the amount of fuel they burn. This reduces the amount of emission as they try to keep the air-to-fuel ratio very close to the stoichiometric point, which is the calculated ideal ratio of air to fuel. 

Xuanlin: Furthermore, we can also reduce the usage of air-conditioners, which releases CFCs as well. Refrigerators have also the ability to produce CFCs, therefore, one very good idea is to purchase environmentally friendly refrigerators available  in the market which produce less CFCs. As burning of plastics will result in the release of CFCs, controlled quota of  burning and the promoting of recycling will reduce the usage of plastic. Thus, it will be a solution to unburnt hydrocarbons as less hydrocarbons are burnt and thus less hydrocarbon are unburnt too. Treating the CFCs produced in power plants may also be one potential solution to be explored in the future, just like how sulfur dioxide is treated to be less harmful to the atmosphere. Lastly, photochemical smog is formed by reactions between sunlight and pollutants, like hydrocarbons and nitrogen dioxide.

Yujia: Photochemical smog is extremely harmful, leading to irritations of the respiratory tract and eyes. In regions of the world with high concentrations of photochemical smog, elevated rates of death and respiratory illnesses have been observed. Smog itself is simply airborne pollution which may obscure vision and cause various health conditions. It is caused by small particles of material which become concentrated in the air for a variety of reasons. Commonly, smog is caused by an inversion, in which cool air presses down on a column of warm air, forcing the air to remain stationary. Inversions are notorious in Southern California, where smog can sometimes get so severe that people are warned to stay indoors. 

Yunting: Some measures have been taken around the world to reduce photochemical smog. Tight emissions regulations on vehicles and factories are one such step; many factories must use scrubbers and treatment systems before releasing air from their manufacturing facilities, for example. The use of harmful chemicals is also restricted in some regions of the world. Since these chemicals can create photochemical smog. Government agencies also monitor air quality through testing, citing companies which violate the law and issuing warnings when smog levels are dangerous.

Yunting: In conclusion, it is evident that the depletion of ozone layer is caused by chlorofluorocarbons, emissions from factories and photochemical smog. From human activities like the products we use daily, the gas emissions released during combustion to the pollutants in the air we inhale..Every action constitutes to ozone gas in the stratosphere declining at a rapid rate. To add on, chlorine atoms in CFCs catalyzes the chemical reactions taking place at the stratosphere. In other words, the tropospheric ozone formation is occurring at a slower rate than the depletion of ozone layer due to its complex chemical reactions such as photodissociation. The depletion of ozone is therefore viewed as an environmental issue that has to be constantly reviewed to develop in the solutions to better overcome the current health problems that were brought forth by the ozone depletion.

Note: all contents are self-produced with help of research, for reference only.

Thursday 6 September 2012

Extraction of zinc from zinc blende

Zinc blende is ground and concentrated by Froth floatation, a process for selectively separating hydrophobic materials from hydrophilic. This is where a powerful air current is blown through the suspension, creating dense foam on its surface, and then the foam is skimmed away, settling the gangue of the zinc ore, concentrating it. Roasting it in air, impure zinc oxide is produced ( 2ZnS(s) + 3O2 (g)à 2ZnO(s) + 2SO2 (g) ) by combustion. The zinc ore can calcined to produce zinc oxide, added with coke/carbon as reducing agent and limestone, and heated at 1673 K in fire clay retorts by Belgian Process (ZnCO3(s) à  ZnO (s) + CO2 (g)), an endothermic thermal decomposition. At this high temperature, the metal is volatile so it distils over and is condensed, leaving behind impurities (ZnO(s) + C(g) = Zn(s) +CO(g)). The crude metal is spelter. The metal may be refined either by electrolysis or by fractional distillation. The zinc is fractionally distilled from the mixture of slag (mud like material insoluble in molten metal) and other metals like lead, iron and cadmium out of the top of the furnace with carbon monoxide atmosphere, preventing zinc from being oxidised back to zinc oxide. The resulting layers can be tapped off. It is refined more by dissolving it in sulfuric acid and purified electrolytically. After reacting ZnO (s)+ H2SO4 (aq) à ZnSO4 (aq) + H2O (l), the zinc sulfate is electrolysed to get zinc.

http://www.transtutors.com/chemistry-homework-help/d-and-f-block-elements/zinc-and-its-compounds.aspx ; http://www.newton.dep.anl.gov/askasci/chem03/chem03435.htm ;
http://www.docbrown.info/page04/Mextractd.htm


> http://cst-www.nrl.navy.mil/lattice/struk/b3.html*). [image: Picture of> lattice; Click for Big Picture]
> http://cst-www.nrl.navy.mil/lattice/struk/b3.html(Watch> video on structure of Zinc Blende:*
> http://www.youtube.com/watch?v=m_7z-7dp8BQ&feature=player_detailpage*)

The extraction of Zinc from Zinc Blende: Reduction has to be carried out in closed vessels or furnaces in which where the zinc vapor can be condensed in the absence of air. For thermal reduction the concentrate is roasted a treatment that may be carried out in two stages multiple-hearth furnace followed by sintering on a traveling grate or in a single-stage operation in which a proportion of the roaste material is fed back to the sintering machine. Sintering is necessary for transforming the material into suitable lumps to allow air to flow through it during the subsequent reduction process.  Reduction of the zinc oxide can be done by various methods. In the so-called standard process, reduction is effected in horizontal retorts in a retort furnace or distilling furnace, which comprises a lower part containing regenerative chambers for preheating of  the gas and combustion air and an upper part in which retorts, arranged in tiers one above the other, are heated by the hot-flame gases. A retort of this kind is a rectangular distilling vessel, about 6or 7ft. long and about 1 ft. square in cross section. It is made of fireclay and has only a short service life, having to be renewed every four to six weeks. The zinc vapor escapes from the retorts and is collected in the condensers as liquid metal. At the end of about 20 hours the process has been completed; the liquid zinc and zinc dust are then removed from the condensers, and the residual matter is removed from the retorts by special machines. In the New Jersey process  reduction is effected in large vertical retorts about 14m (45 ft) high and of rectangular cross section, lined with silicon-carbide bricks in the hottest parts. The advantage over the horizontal retort method is that reduction can be performed as a continuous operation. The charge consist of briquettes made of a mixture of zinc oxide material (roasted blende) and bituminous coal. The briquettes are fed automatically to the resort, the residual matter being extracted by a screw conveyor at the bottom. The mixture of carbon monoxide and zinc vapor is discharged from the top of the retort into a condenser, where the metal is precipitated in liquid form.
Chemical Formula: (Zn,Fe 2+)S
Mineral Name: Spharelite
Color:Yellowish brown, orange, red, black, greenish yellow.
Hardness: 3.5 - 4
Specific Gravity: 3.9 - 4.1

Impact on the environment and its soloution

-cadmium vapour - severe lung irritation, pulmonary edema, and in some cases, death; long term inhalation of it can cause emphysema, a disease affecting the ability of the lung to absorb oxygen) and can damage the kidneys.

-Carbon dioxide emitted by machines (e.g., dieselpowered
heavy vehicles) involved in extracting
and transporting ore: cause global warming.  Reduce by planting more trees and maintaining forest & nature … 


Zinc in rivers – Decrease amount of oxygen carrying capacities of blood in fish
 -Main cause is the sulfur dioxide produced which is poisonous; at a level of 0.5%, it will kill. It reacts with rain water to cause acid rain, which can affect animals and plants & corrode buildings. The immediate effects of inhaling sulfur dioxide on humans are coughing, chest pains and breathlessness. Sulfur dioxide is thought to contribute to bronchitis and lung diseases. Sulfur dioxide react with water vapour to form acid rain. Acid rain can damage lakes and fish, trees and building materials such as stone, concrete, metal and cement. This can affect the environment by just changing the pH. It can be reduced by changing it into other useful industrial materials.
 
 
http://www.mechanicalebook.com/topics/topicz/zinc.htm)